2015 UPDATE: 15 questions & answers have been added to the 313D exam.The 313D practice exam consists of 132 multiple choice questions & answers, which are in the private forum.
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HereI posted a scan of the instructions I had for anyone who wants to apply for the 313D certificate, without going through the Apprenticeship program.
You need a letter from your employer, on a company letterhead which give the company address, exact dates of employment, and number of hours worked. Include the name of the certificate holder who is assessing you. Your employer should have no problem crediting you with 4500 hours. Your 313D certificate will benefit him as well. No one in the MTCU will cross reference you record of employment. If you have 4500 hours working on air conditioners, then you have every right to challenge the 313D exam.
The certificate holder and employer sign off on the residential air conditioning mechanic supervisor's assessment of skill sets document, and the competency analysis profile form.
Send that to the ministry and wait until they contact you with exam dates.